Ce
Cerium Energy Research Group
Fundamental & Applied Research

Hydrogen Research
Laboratory

CeO₂ → CeO₂₋ₓ + ½O₂  |  CeO₂₋ₓ + H₂O → CeO₂ + H₂

Advancing thermochemical water‑splitting processes based on cerium oxide for carbon‑free hydrogen generation — from fundamental redox mechanisms to high‑temperature reactor systems.

Key Parameters
>1400°C
Reduction Temperature
2‑Step
Redox Cycle
0 CO₂
Carbon Emissions
H₂ ↑
Clean Hydrogen Output
Research Focus

Our Scientific Work

The Hydrogen Production Laboratory conducts fundamental and applied research on thermochemical water‑splitting processes based on cerium oxide (CeO₂), focusing on redox mechanisms, material performance, and high‑temperature systems.

Materials
Material Investigation

Investigation of CeO₂ and doped ceria materials for enhanced redox activity, focusing on oxygen vacancy formation and ionic conductivity optimisation.

Kinetics
Kinetics Analysis

Characterisation of oxygen release and uptake kinetics under high‑temperature conditions, enabling precise control of the thermochemical cycle.

Engineering
Reactor Development

Development of thermochemical cycles for solar‑driven or electrically heated reactors, bridging laboratory findings to scalable industrial systems.

Analysis
Quantitative Analysis

Quantitative analysis of hydrogen yield, reaction efficiency, and material stability across multiple cycles to validate performance metrics.

Thermochemical Water‑Splitting

The Two‑Step Redox Cycle

Cerium oxide enables a closed redox loop. Each step is thermodynamically distinct, allowing the material to be regenerated indefinitely while producing hydrogen as the sole reaction product.

Step 01
High‑Temperature Reduction
≥ 1400 °C

Under elevated temperatures, CeO₂ undergoes partial reduction, forming oxygen‑deficient CeO₂₋ₓ and releasing molecular oxygen.

CeO₂ → CeO₂₋ₓ + x/2 O₂
Step 02
Hydrolysis / Re‑oxidation
~800 °C + H₂O

The reduced oxide reacts with steam, regenerating CeO₂ while producing hydrogen as the sole reaction product.

CeO₂₋ₓ + x H₂O → CeO₂ + x H₂

This cycle represents a promising route for sustainable hydrogen generation, particularly when integrated with concentrated solar power or other renewable high‑temperature energy sources.

Mission & Objectives

What We Aim to Achieve

Our mission is to advance the scientific understanding and technological readiness of ceria‑based thermochemical systems — from atomic‑scale redox mechanisms to pilot‑scale reactor designs — contributing to the global transition toward clean hydrogen technologies.

  • 01Improve redox efficiency through advanced material engineering and doping strategies
  • 02Enhance long‑term material stability under cyclic high‑temperature operation
  • 03Develop scalable reactor concepts suitable for industrial implementation
  • 04Contribute to the global transition toward clean hydrogen technologies
Redox Cycle
Ce⁴⁺ Ce³⁺ O₂ H₂ HIGH TEMP HYDROLYSIS
Structural Stability

CeO₂ ceramic foam architectures provide exceptional surface area and structural integrity across repeated high‑temperature thermal cycles — essential for long‑term reactor performance.

Our People Team

Meet the researchers and administrators behind the Cerium Energy Research Group.

Dragoș Mihail
Dragoș Mihail
Research Coordinator
Victor Pîslari
Victor Pîslari
Research Engineer
Daniela Pîslari
Daniela Pîslari
Research Administrator
Contact

Get in Touch

We welcome academic collaborations, research partnerships, and inquiries about our thermochemical hydrogen production work. Whether you are a researcher, engineer, or industry partner — reach out to discuss how we can advance clean hydrogen together.

CERIUM ENERGY RESEARCH GROUP
Company Number: 16980064

Registered in England and Wales.
Thermochemical Research Division.